The Effect of a Novel Surface Modified Nanoparticles on Wettability Alteration and Enhanced Oil Recovery

[1] Ali, J.A., Kolo, K., Khaksar-Manshad, A., Stephen, K.D., 2021, Emerging applications of TiO₂/SiO₂/poly (acrylamide) nanocomposites within the engineered water EOR in carbonate reservoirs, Journal of Molecular Liquids, 322, 114943. https://doi.org/10.1016/j.molliq.2020.114943

[2] Jafarbeigi, E., Mohammadidoust, A, Ranjbar, B., 2022, A review on applications of nanoparticles in the enhanced oil recovery in car­bonate reservoirs, Petroleum Science and Technology, 40(11), 1-18. https://doi.org/10.1080/10916466.2022.2030358

[3] Ahmadi, Y., Akbari, A., Mansouri, M., Alibak, A.H., Vaferi, B., 2024, Innovative xanthan gum-based nanocomposites for asphaltene precipitation prevention in shale and carbonate rocks‏, International Journal of Biological Macromolecules, 280, 136331‏. https://doi.org/10.1016/j.ijbiomac.2024.136331

[4] Nazarahari, M.J., Khaksar-Manshad, A., Moradi, S., Shafiei, A., Ali, J.A., Sajadi, S.M., Keshavarz, A., 2020, Synthesis, Characterization, and Assessment of a CeO₂@Nanoclay Nanocomposite for Enhanced Oil Recovery, Nanomaterials, 10(11), 2280. https://doi.org/10.3390/nano10112280

[5] Mirzavandi, M., Ali, J.A., Khaksar-Manshad, A., Majeed, B., Mahmood, B.S., Mohammadi, A.H., Iglauer, S., Keshavarz, A., 2023, Performance Evaluation of Silica–Graphene Quantum Dots for Enhanced Oil Recovery from Carbonate Reservoirs, Energy & Fuels, 37(2), 955-964. https://doi.org/10.1021/acs.energyfuels.4c05872

[6] Saghandali, F., Salehi, M.B., Pahlevani, H., Taghikhani, V., Riahi, S., Ebrahimi, M., Saviz, S., Roomi, A., 2024, Fabrication of a hydrogel reinforced with titanium nanoparticles to reduce fine migration and remediation of formation damage during low-salinity water flooding, Geoenergy Science and Engineering, 241, 213173. https://doi.org/10.1016/j.geoen.2024.213173

[7] Jha, N.K., Ali, M., Iglauer, S., Lebedev, M., Roshan, H., Barifcani, A., Sangwai, J.S., Sarmadivaleh, M., 2019, Wettability alteration of quartz surface by low-salinity surfactant nanofluids at high-pressure and high-temperature conditions, Energy Fuels, 33, 7062–7068. https://doi.org/10.1021/acs.energyfuels.9b01102

[8] Jha, N.K., Iglauer, S., Barifcani, A., Sarmadivaleh, M., Sangwai, J.S., 2019, Low-salinity surfactant nanofluid formulations for wettability alteration of sandstone: role of the SiO₂ nanoparticle concentration and divalent cation/SO₄^{2 –} ratio, Energy Fuels, 33, 739–746. https://doi.org/10.1021/acs.energyfuels.8b03406

[9] Xu, Z.X., Li, S.Y., Li, B.F., Chen, D.Q., Liu, Z.Y., Li, Z.M., 2020, A review of development methods and EOR technologies for carbonate reservoirs, Petroleum Science, 17(4), 990–1013. https://doi.org/10.1007/s12182-020-00467-5

[10] Katende, A., Sagala, F., 2019, A critical review of low salinity water flooding: mechanism, laboratory and field application, Journal of Molecular Liquids., 278, 627–649. https://doi.org/10.1016/j.molliq.2019.01.037

[11] Mariyate, J, Bera, A., 2021, Recent progresses of microemulsions-based nanofluids as a potential tool for enhanced oil recovery, Fuel, 306, 121640. https://doi.org/10.1016/j.fuel.2021.121640

[12] Sun, X.F., Zhang, Y.Y., Chen, G.P., Gai, Z.Y., 2017, Application of nanoparticles in enhanced oil recovery: a critical review of recent progress, Energies, 10(3), 345. https://doi.org/10.3390/en10030345

[13] Pourafshary, P., Moradpour, N., 2019, Hybrid EOR methods utilizing low-salinity water, Enhanced Oil Recovery Processes - New Technologies, 8, 25. https://doi.org/10.5772/intechopen.88056

[14] Wu, S., Nikolov, A., Wasan, D., 2013, Cleansing dynamics of oily soil using nanofluids, Journal of Colloid and Interface Science, 396, 293–306. https://doi.org/10.1016/j.jcis.2013.01.036

[15] Jafarbeigi, E., Sahraei, E., Maroufi, K‏., 2025, A novel functionalized nanoparticle for inhibiting asphaltene precipitation and deposition, Physics of Fluids, 37(1)‏, 017164. https://doi.org/10.1063/5.0249699

[16] Jafarbeigi, E., Shahini-Nia, M., Mansouri, M., Kikhavani, T., Setareshenas, N., 2025, CuO/Al₂O_3/carbomer as a new hybrid agent for wettability alteration and oil recovery in carbonate reservoirs, Journal of Molecular Liquids, 425, 127270‏. https://doi.org/10.1016/j.molliq.2025.127270

[17] Gholinezhad, S., Kantzas, A., Bryant, S.L., 2022, Effect of surface func­tionalized silica nanoparticles on interfacial behavior: Wettability, interfacial tension and emulsification characteristics, Journal of Molecular Liquids, 349, 118220. https://doi.org/10.1016/j.molliq.2021.118220

[18] Razavifar, M., Khoshsima, A., Riazi, M., Sheng, J.J., Esmaeilnezhad, E., 2024, Recent developments, challenges, and prospects of carbon dots (CDs) for fluid flow investigation in porous media, Petroleum Research, 9(4), 553-564. https://doi.org/10.1016/j.ptlrs.2024.04.004

[19] Sakthivel, S., Zhou, X., Giannelis, E.P., Kanj, M.Y., 2021, Carbon nanodots for enhanced oil recovery in carbonate reservoirs, Energy Reports, 7, 8943-8959. https://doi.org/10.1016/j.egyr.2021.11.194

[20] Aminian, A., ZareNezhad, B., 2019, Oil-detachment from the calcium carbonate surfaces via the actions of surfactant, nanoparticle and low salinity brine: an insight from molecular dynamic simulation, Chemical Engineering Science, 202, 373–82.    https://doi.org/10.1016/j.ces.2019.03.031

[21] Deng, X., Kamal, M.S., Patil, S., Hussain, S.M.S., Zhou, X., 2020, A review on wettability alteration in carbonate rocks: wettability modifiers, Energy Fuel, 34, 31–54. https://doi.org/10.1021/acsomega.4c07387

[22] Moghadasi, R., Rostami, A., Hemmati-Sarapardeh, A., Motie, M., 2019, Application of Nanosilica for inhibition of fines migration during low salinity water injection: experimental study, mechanistic understanding, and model development, Fuel, 242, 846–62. https://doi.org/10.1016/j.fuel.2019.01.053

[23] Mansouri, M., Ahmadi, Y., Sedghamiz, M.A., Vaferi, B.‏, 2024, Experimental investigation of the influence of ZnO–CuO nanocomposites on interfacial tension, contact angle, and oil recovery by spontaneous imbibition in carbonate rocks‏, Physics of Fluids, 36(10). https://doi.org/10.1063/5.0231237

[24] Ahmadi, Y., Sadeghi, Z., Kikhavani, T., Alibak, A.H., Vaferi, B.‏, 2024, Synthesis and application of eucalyptus plant- and walnut shell- CuO/Fe₃O₄/Xanthan polymeric nanocomposites for enhanced oil recovery in carbonate reservoirs‏, Journal of Petroleum Exploration and Production Technology, 14, 3045–3054‏. https://doi.org/10.1007/s13202-024-01861-0

[25] Ali, J.A., Kolo, K., Khaksar-Manshad, A., Mohammadi, A.H., 2018, Recent advances in application of nanotechnology in chemical enhanced oil recovery: Effects of nanoparticles on wettability alteration, interfacial tension reduction, and flooding, Egyptian journal of petroleum, 27(4), 1371-1383. https://doi.org/10.1016/j.ejpe.2018.09.006

[26] Jafarbeigi, E., Ayatollahi, S., Ahmadi, Y., Mansouri, M., Dehghani, F.‏, 2023, Identification of novel applications of chemical compounds to change the wettability of reservoir rock: A critical review‏, Journal of Molecular Liquids, 371, 121059‏. https://doi.org/10.1016/j.molliq.2022.121059

[27] Iravani, M., Simjoo, M., Molaei, A.H., ‏2025, Synergistic effect of polymer and graphene oxide nanocomposite in heterogeneous layered porous media: a pore-scale EOR Study‏, Journal of Petroleum Exploration and Production Technology 15(1), 9. https://doi.org/10.1007/s13202-024-01910-8

[28] Jafarbeigi, E., Salimi, F., Kamari, E., Mansouri, M., ‏2022, Effects of modified graphene oxide (GO) nanofluid on wettability and IFT changes: Experimental study for EOR application, Petroleum Science, 19(4), 1779-1792. https://doi.org/10.1016/j.petsci.2021.12.022

[29] Salimi, F., Jafarbeigi, E., Karami, C., Khodapanah, E.‏, 2024, Synthesis of cost-effective Si-CQD for effective oil separation from core rock‏, Journal of Molecular Liquids, 394, 123722‏. https://doi.org/10.1016/j.molliq.2023.123722

[30] Shadervan, A., Jafari, A., Teimouri, A., Gharibshahi, R., Dehaghani, A.H.S., 2024, Mechanistic understanding of asphaltene precipitation and oil recovery enhancement using SiO₂ and CaCO₃ nano-inhibitors, Scientific Reports, 14(1), 15249. https://doi.org/10.1038/s41598-024-65995-1

[31] Gharibshahi, R., Mehrooz, N., Jafari, A., 2024, In-Situ Synthesis of Nanoparticles for Enhanced Oil Recovery (EOR) Operations: Current Status and Future Prospects, Innovations in Enhanced and Improved Oil Recovery - New Advances, IntechOpen. https://doi.org/10.5772/intechopen.1003216

[32] Miranda, C.R., Lara, L.S.D., Tonetto, B.C., 2012, Stability and mobility of functionalized silica nanoparticles for enhanced oil recovery applications, SPE international oilfield nanotechnology conference and exhibition, Society of Petroleum Engineers Journal, Paper Number: SPE-157033-MS. https://doi.org/10.2118/157033-MS

[33] Esmaeilnezhad, E., Jin Choi, H., Schaffie, M., Gholizadeh, M., Ranjbar, M., 2018, Polymer coated magnetite-based magnetorheological fluid and its potential clean procedure applications to oil production, Journal of Cleaner Production, 171, 45–56 (2018). https://doi.org/10.1016/j.jclepro.2017.10.004

[34] Khajeh Kulaki, A., Hosseini-Nasab, S.M., Hormozi, F., 2024, Low-salinity water flooding by a novel hybrid of nano γ-Al₂O₃/SiO₂ modified with a green surfactant for enhanced oil recovery, Scientific Report., 14(1), 14033. https://doi.org/10.1038/s41598-024-64171-9

[35] Ali, J.A, Kolo, K., Khaksar-Manshad, A., Stephen, K.D., 2019, Potential application of low-salinity polymeric-nanofluid in carbonate oil reservoirs: IFT reduction, wettability alteration, rheology and emulsification characteristics, Journal of Molecular Liquids, 284, 735-747. https://doi.org/10.1016/j.molliq.2019.04.053

[36] Habibi, S., Jafari, A., Fakhroueian, Z., 2020, Wettability alteration analysis of smart water/novel functionalized nanocomposites for enhanced oil recovery,Petroleum Science, 17, 1318-1328. https://doi.org/10.1007/s12182-020-00436-y

[37] Habibi, S., Jafari, A., Fakhroueian, Z., 2020, Application of novel functionalized Al₂O₃/silica by organosiloxane and amine reagents for enhanced oil recovery, Applied Nanoscience, 10, 2085-2100. https://doi.org/10.1007/s13204-020-01337-7

[38] Liang, F., Wang, W., Zhu, S., Hu, Y., Zhao, Z., Tan, Y., Yu, G., Hou, J., Li, J., 2024, Nanofluids application in enhanced oil recovery process-opportunities and challenges, Arabian Journal of Chemistry, 18(1), 106053.  https://doi.org/10.1016/j.arabjc.2024.106053

[39] Omidi, A., Khaksar-Manshad, A., Moradi, S., Ali, J.A., Sajadi, S.M., Keshavarz, A., 2020, Smart-and nano-hybrid chemical EOR flooding using Fe₃O₄/eggshell nanocomposites, Journal of Molecular Liquids, 316, 113880. https://doi.org/10.1016/j.molliq.2020.113880

[40] Kobayashi, M., Juillerat, F., Galletto, P., Bowen, P., Borkovec, M., 2005, Aggregation and charging of colloidal silica particles: effect of particle size, Langmuir, 21, 5761–5769. https://doi.org/10.1021/la046829z

[41] Ahmadi, M., Habibi, A., Pourafshry, P., Ayatollahi, S., 2011, Zeta Potential Investigation and Mathematical Modeling of Nanoparticles Deposited on the Rock Surface to Reduce Fine Migration, SPE Middle East Oil and Gas Show and Conference.    https://doi.org/10.2118/142633-MS

[42] Lee, J., Hwang, K., Jang, S., Lee, B., Kim, J.H., Choi, S., Choi, C., 2008, Effective viscosities and thermal conductivities of aqueous nanofluids containing low volume concentrations of Al₂O₃ nanoparticles,International Journal of Heat and Mass Transfer, 51, 2651–2656. https://doi.org/10.1016/j.ijheatmasstransfer.2007.10.026

[43] Jafarbeigi, E., Kamari, E., Salimi, F., Mohammadidoust, A.,  2020, Experimental study of the effects of a novel nanoparticle on enhanced oil recovery in carbonate porous media, Journal of Petroleum science and Engineering, 195, 107602. https://doi.org/10.1016/j.petrol.2020.107602

[44] Wasan, DT., Nikolov, A.D., 2003, Spreading of nanofluids on solids, Nature, 423, 156-159. https://doi.org/10.1038/nature01591

[45] Zargar, G., Arabpour, T., Khaksar-Manshad, A., Ali, J.A., Sajadi, S.M., Keshavarz, A., Mohammadi, A.H., 2020, Experimental investigation of the effect of green TiO₂/Quartz nanocomposite on interfacial tension reduction, wettability alteration, and oil recovery improvement, Fuel, 263, 116599. https://doi.org/10.1016/j.fuel.2019.116599

[46] Khaksar-Manshad, A., Ali, J.A., Haghighi, O.M., Sajadi, S.M., Keshavarz, A., 2022, Oil recovery aspects of ZnO/SiO₂ nano-clay in the carbonate reservoir, Fuel, 307, 121927. https://doi.org/10.1016/j.fuel.2021.121927

[47] Zhang, P., Tweheyo, M.T., Austad, T., 2007, Wettability alteration and improved oil recovery by spontaneous imbibition of seawater into chalk: Impact of the potential determining ions Ca²⁺, Mg²⁺, and SO₄²⁻, Colloids and Surfaces A Physicochemical and Engineering Aspects, 301(1-3),199-208. https://doi.org/10.1016/j.colsurfa.2006.12.058

[48] Keykhosravi, A., Bagheri Vanani, M., Aghayari, C., 2021, TiO₂ nanoparticle-induced Xanthan Gum Polymer for EOR: Assessing the underlying mechanisms in oil-wet carbonates, Journal of Petroleum Science and Engineering, 204, 108756. https://doi.org/10.1016/j.petrol.2021.108756

[49] Cheraghian, G., 2016, Effect of nano titanium dioxide on heavy oil recovery during polymer flooding, Petroleum Science and Technology, 34(7), 633-641. https://doi.org/10.1080/10916466.2016.1156125

[50] Garmroudi, A., Kheirollahi, M., Mousavi, S.A., Fattahi, M., Hamed Mahvelati, E., 2022, Effects of graphene oxide/TiO₂ nanocomposite, graphene oxide nanosheets and Cedr extraction solution on IFT reduction and ultimate oil recovery from a carbonate rock, Petroleum, 8(4), 476-482. https://doi.org/10.1016/j.petlm.2020.10.002

[51] Li, Y., Zou, C., Kang, J., You, J., Liu, E., Wang, Y., Cao, Y., 2024, β-Cyclodextrin modified SiO₂ nanofluid for enhanced oil recovery, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 688, 133655.    https://doi.org/10.1016/j.colsurfa.2024.133655

[52] Kandiel, Y.E., Attia, G., Metwalli, F., Khalaf, R., Mahmoud, O., 2025, Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery, Energies, 18(2), 249. https://doi.org/10.3390/en18020249