| تعداد نشریات | 31 |
| تعداد شمارهها | 834 |
| تعداد مقالات | 8,015 |
| تعداد مشاهده مقاله | 14,852,479 |
| تعداد دریافت فایل اصل مقاله | 9,586,507 |
A Mini-Review on Biodiesel Production using Zeolite-Based Catalysts | ||
| Chemical Process Design | ||
| دوره 4، شماره 2، اسفند 2025، صفحه 50-63 اصل مقاله (797.93 K) | ||
| نوع مقاله: Review Article | ||
| شناسه دیجیتال (DOI): 10.22111/cpd.2025.51871.1056 | ||
| نویسندگان | ||
| Mohammad Radi؛ Ensie Bekhradinassab* | ||
| Chemical Engineering Department, Faculty of Engineering, Behbahan Khatam Alanbia University of Technology, Behbahan, Iran. | ||
| چکیده | ||
| With increasing environmental concerns and the depletion of fossil fuels, biodiesel has emerged as a crucial renewable energy alternative. Among various production methods, zeolite-based solid catalysts have gained significant attention due to their high surface area, thermal stability, and reusability. Unlike traditional liquid alkaline catalysts, zeolites reduce soap formation, corrosion, and purification requirements, making them more efficient and environmentally friendly. However, challenges such as mass transfer limitations in micropores, sensitivity to feedstock impurities, and stability under harsh reaction conditions remain obstacles to their widespread adoption. This mini-review explores recent advancements in acidic, bi-functional, and basic zeolite catalysts for biodiesel production via esterification and transesterification. Strategies to overcome existing limitations, such as hierarchical pore design, surface modification, and composite formation, are discussed. Future research directions focus on nanostructure engineering and multifunctional composites to improve catalytic performance, durability, and cost-effectiveness. Despite current technical hurdles, zeolites demonstrate strong potential for sustainable biodiesel production. Continued innovation in catalyst design and process optimization could further enhance their efficiency, making them a viable solution for cleaner energy generation. The findings emphasize the importance of zeolite catalysts in advancing renewable fuel technologies while addressing environmental and economic concerns. | ||
| کلیدواژهها | ||
| Magnetic nanoparticles؛ Salen Ru(OTf)₂؛ Acetylation؛ Alcohol acetylation؛ Phenol acetylation؛ Schiff base؛ Recyclable Nano catalyst | ||
| مراجع | ||
|
[1] Bekhradinassab, E., Tavakoli, A., Haghighi, M., Shabani, M., 2022. Catalytic biofuel production over 3D macro-structured cheese-like Mn-promoted TiO2 isotype: Mn-catalyzed microwave-combustion design. Energy Conversion and Management, 251, 114916. https://doi.org/10.1016/j.enconman.2021.114916
[2] Bekhradinassab, E., Ghasemi, I., 2025. Synthesis of Fe2O3-supported lightweight expanded clay aggregate (LECA) via solution combustion: An innovative and cost-effective catalyst for biodiesel generation. Surfaces and Interfaces, 106582. https://doi.org/10.1016/j.surfin.2025.106582
[3] Bekhradinassab, E., Haghighi, M., Tavakoli, A., Shabani, M., 2022. Mn-Fe catalyzed microwave combustion-plasma hybrid synthesis of 2D chips-like Mn-Fe boosted TiO2 architecture self-assembled of nano-walled honeycomb-like super-macroporous: Green fuel generation. Energy Conversion and Management, 270, 116178. https://doi.org/10.1016/j.enconman.2022.116178
[4] Sun, K., Lu, J., Ma, L., Han, Y., Fu, Z., Ding, J., 2015. A comparative study on the catalytic performance of different types of zeolites for biodiesel production. Fuel, 158, 848–854. https://doi.org/10.1016/j.fuel.2015.06.048
[5] Bekhradinassab, E., Haghighi, M., Shabani, M., 2025. A review on acidic metal oxide-based materials towards heterogeneous catalytic biodiesel production via esterification process. Fuel, 379, 132986. https://doi.org/10.1016/j.fuel.2024.132986
[6] Baroi, C., Mahto, S., Niu, C., Dalai, A.K., 2014. Biofuel production from green seed canola oil using zeolites. Applied Catalysis A: General, 469, 18–32. https://doi.org/10.1016/j.apcata.2013.09.034
[7] Arumugam, M., Goh, C.K., Zainal, Z., Triwahyono, S., Lee, A.F., Wilson, K., Taufiq-Yap, Y.H., 2021. Hierarchical HZSM-5 for catalytic cracking of oleic acid to biofuels. Nanomaterials, 11 (3), 747. https://doi.org/10.3390/nano11030747
[8] Ghasemi, I., Haghighi, M., Bekhradinassab, E., 2025. Microwave assisted combustion design and performance screening of NiM2O4 (M: Zn and Mn) spinels enhanced by lamellar porous graphene oxide nanosheets for biodiesel production. Journal of Environmental Chemical Engineering, 116263. https://doi.org/10.1016/j.jece.2025.116263
[9] Bekhradinassab, E., Tavakoli, A., Haghighi, M., Shabani, M., 2023. 2-Hydroxyethylammoniumsulfate ionic liquid performance as simultaneous fuel and sulfating agent in tablet-like manganese and iron incorporated titania synthesis: Biodiesel production from waste oil. Fuel, 340, 127402. https://doi.org/10.1016/j.fuel.2023.127402
[10] Ebrahimi, A., Haghighi, M., Ghasemi, I., Bekhradinassab, E., 2024. Design of highly recoverable clay-foundation composite of plasma-treated Co3O4/Kaolin to produce biodiesel from low-cost oil. Fuel, 366, 131267. https://doi.org/10.1016/j.fuel.2024.131267
[11] Shokrani, R., Haghighi, M., Mohammadpour, M., 2022. Influence of ultrasound irradiation power on surface design of CaO nanoparticles over secondary carbon-templated meso designed ZSM-5 for biofuel production from vegetable oil. Fuel, 323, 124387. https://doi.org/10.1016/j.fuel.2022.124387
[12] Ghasemi, I., Haghighi, M., Bekhradinassab, E., Ebrahimi, A., 2024. Ultrasound-assisted dispersion of bifunctional CaO-ZrO2 nanocatalyst over acidified kaolin for production of biodiesel from waste cooking oil. Renewable Energy, 225, 120287. https://doi.org/10.1016/j.renene.2024.120287
[13] Al-Ani, A., Freitas, C., Zholobenko, V., 2020. Nanostructured large-pore zeolite: The enhanced accessibility of active sites and its effect on the catalytic performance. Microporous and Mesoporous Materials, 293, 109805. https://doi.org/10.1016/j.micromeso.2019.109805
[14] Wang, X., Guo, S., Song, P., Xu, L., Zhang, X., Shen, B., 2024. Synthesis and catalytic performance of hierarchically porous catalysts during pyrolysis of lipids to produce liquid hydrocarbons: A review. Applied Catalysis A: General, 677, 119704. https://doi.org/10.1016/j.apcata.2024.119704
[15] Arhancet, J.P., Davis, M.E., 1991. Systematic synthesis of zeolites that contain cubic and hexagonal stackings of faujasite sheets. Chemistry of Materials, 3 (4), 567–569. https://doi.org/10.1021/cm00016a001
[16] Shokrani, R., Haghighi, M., 2020. Textural evolution of hierarchical nanostructured ZSM-5 via sono-hydrothermal design by various carbon shapes for efficient biodiesel production. Applied Catalysis B: Environmental, 271, 118940. https://doi.org/10.1016/j.apcatb.2020.118940
[17] Wang, C., Wang, L., Du, F., Yu, Q., Liang, X., 2023. A two-step organic modification strategy for improving surface hydrophobicity of zeolites. Advanced Powder Technology, 34 (11), 104228. https://doi.org/10.1016/j.apt.2023.104228
[18] Chai, M., Tu, Q., Lu, M., Yang, Y.J., 2014. Esterification pretreatment of free fatty acid in biodiesel production, from laboratory to industry. Fuel Processing Technology, 125, 106–113. https://doi.org/10.1016/j.fuproc.2014.03.025
[19] Al-Jammal, N., Al-Hamamre, Z., Alnaief, M., 2016. Manufacturing of zeolite based catalyst from zeolite tuft for biodiesel production from waste sunflower oil. Renewable Energy, 93, 449–459. https://doi.org/10.1016/j.renene.2016.03.018
[20] Li, J., Gao, M., Yan, W., Yu, J., 2023. Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties. Chemical Science, 14 (8), 1935–1959. https://doi.org/10.1039/D2SC06010H
[21] Munthali, M.W., Elsheikh, M.A., Johan, E., Matsue, N., 2014. Proton adsorption selectivity of zeolites in aqueous media: Effect of Si/Al ratio of zeolites. Molecules, 19 (12), 20468–20481. https://doi.org/10.3390/molecules191220468
[22] Liu, M., Li, N., Cao, S., Wang, X., Lu, X., Kong, L., Xu, Y., Bu, X.-H., 2022. A “Pre-Constrained Metal Twins” strategy to prepare efficient dual-metal-atom catalysts for cooperative oxygen electrocatalysis. Advanced Materials, 34 (7), 2107421. https://doi.org/10.1002/adma.202107421
[23] Osatiashtiani, A., Puértolas, B., Oliveira, C.C.S., Manayil, J.C., Barbero, B., Isaacs, M., Michailof, C., Heracleous, E., Pérez-Ramírez, J., Lee, A.F., Wilson, K., 2017. On the influence of Si:Al ratio and hierarchical porosity of FAU zeolites in solid acid catalysed esterification pretreatment of bio-oil. Biomass Conversion and Biorefinery, 7 (3), 331–342. https://doi.org/10.1007/s13399-017-0254-x
[24] Yusuf, B.O., Oladepo, S.A., Ganiyu, S.A., 2023. Zr-modified desilicated ZSM-5 catalysts as highly active and recyclable catalysts for production of biodiesel from soybean oil: Insight into improved catalyst properties, acidity and dispersion through desilication. Fuel, 351, 128729. https://doi.org/10.1016/j.fuel.2023.128729
[25] Sadeghpour, P., Haghighi, M., 2018. High-temperature and short-time hydrothermal fabrication of nanostructured ZSM-5 catalyst with suitable pore geometry and strong intrinsic acidity used in methanol to light olefins conversion. Advanced Powder Technology, 29 (5), 1175–1188. https://doi.org/10.1016/j.apt.2018.02.009
[26] Derbe, T., Temesgen, S., Bitew, M., 2021. A short review on synthesis, characterization, and applications of zeolites. Advances in Materials Science and Engineering, 2021 (1), 6637898. https://doi.org/10.1155/2021/6637898
[27] Du, S., Li, F., Sun, Q., Wang, N., Jia, M., Yu, J., 2016. A green surfactant-assisted synthesis of hierarchical TS-1 zeolites with excellent catalytic properties for oxidative desulfurization. Chemical Communications, 52 (16), 3368–3371. https://doi.org/10.1039/C5CC08441E
[28] Cho, K., Na, K., Kim, J., Terasaki, O., Ryoo, R., 2012. Zeolite synthesis using hierarchical structure-directing surfactants: Retaining porous structure of initial synthesis gel and precursors. Chemistry of Materials, 24 (14), 2733–2738. https://doi.org/10.1021/cm300841v
[29] Wright, P.A., Maple, M.J., Slawin, A.M.Z., Patinec, V., Aitken, R.A., Welsh, S., Cox, P.A., 2000. Cation-directed syntheses of novel zeolite-like metalloaluminophosphates STA-6 and STA-7 in the presence of azamacrocycle templates. Journal of the Chemical Society, Dalton Transactions, (8), 1243–1248. https://doi.org/10.1039/A909249H
[30] Wu, L., Degirmenci, V., Magusin, P.C.M.M., Szyja, B.M., Hensen, E.J.M., 2012. Dual template synthesis of a highly mesoporous SSZ-13 zeolite with improved stability in the methanol-to-olefins reaction. Chemical Communications, 48 (76), 9492–9494. https://doi.org/10.1039/C2CC33994C
[31] White, R.J., Fischer, A., Goebel, C., Thomas, A., 2014. A sustainable template for mesoporous zeolite synthesis. Journal of the American Chemical Society, 136 (7), 2715–2718. https://doi.org/10.1021/ja411586h
[32] Abukhadra, M.R., Ibrahim, S.M., Yakout, S.M., El-Zaidy, M.E., Abdeltawab, A.A., 2019. Synthesis of Na+ trapped bentonite/zeolite-P composite as a novel catalyst for effective production of biodiesel from palm oil; Effect of ultrasonic irradiation and mechanism. Energy Conversion and Management, 196, 739–750. https://doi.org/10.1016/j.enconman.2019.06.027
[33] Wu, H., Zhang, J., Wei, Q., Zheng, J., Zhang, J., 2013. Transesterification of soybean oil to biodiesel using zeolite supported CaO as strong base catalysts. Fuel Processing Technology, 109, 13–18. https://doi.org/10.1016/j.fuproc.2012.09.032
[34] Du, L., Ding, S., Li, Z., Lv, E., Lu, J., Ding, J., 2018. Transesterification of castor oil to biodiesel using NaY zeolite-supported La2O3 catalysts. Energy Conversion and Management, 173, 728–734. https://doi.org/10.1016/j.enconman.2018.07.053
[35] Wang, Y.-Y., Chen, B.-H., 2016. High-silica zeolite beta as a heterogeneous catalyst in transesterification of triolein for biodiesel production. Catalysis Today, 278, 335–343. https://doi.org/10.1016/j.cattod.2016.03.012
[36] Đặng, T.-H., Nguyễn, X.-H., Chou, C.-L., Chen, B.-H., 2021. Preparation of cancrinite-type zeolite from diatomaceous earth as transesterification catalysts for biodiesel production. Renewable Energy, 174, 347–358. https://doi.org/10.1016/j.renene.2021.04.068
[37] Doyle, A.M., Albayati, T.M., Abbas, A.S., Alismaeel, Z.T., 2016. Biodiesel production by esterification of oleic acid over zeolite Y prepared from kaolin. Renewable Energy, 97, 19–23. https://doi.org/10.1016/j.renene.2016.05.067
[38] Carmo, A.C., de Souza, L.K.C., da Costa, C.E.F., Longo, E., Zamian, J.R., da Rocha Filho, G.N., 2009. Production of biodiesel by esterification of palmitic acid over mesoporous aluminosilicate Al-MCM-41. Fuel, 88 (3), 461–468. https://doi.org/10.1016/j.fuel.2008.10.007
[39] Alismaeel, Z.T., Abbas, A.S., Albayati, T.M., Doyle, A.M., 2018. Biodiesel from batch and continuous oleic acid esterification using zeolite catalysts. Fuel, 234, 170–176. https://doi.org/10.1016/j.fuel.2018.07.025
[40] Narkhede, N., Patel, A., 2013. Biodiesel production by esterification of oleic acid and transesterification of soybean oil using a new solid acid catalyst comprising 12-tungstosilicic acid and zeolite Hβ. Industrial & Engineering Chemistry Research, 52 (38), 13637–13644. https://doi.org/10.1021/ie402230v
[41] Buchori, L., Widayat, W., Muraza, O., Amali, M.I., Maulida, R.W., Prameswari, J., 2020. Effect of temperature and concentration of zeolite catalysts from geothermal solid waste in biodiesel production from used cooking oil by esterification–transesterification process. Processes, 8 (12), 1629. https://doi.org/10.3390/pr8121629
[42] Milina, M., Mitchell, S., Pérez-Ramírez, J., 2014. Prospectives for bio-oil upgrading via esterification over zeolite catalysts. Catalysis Today, 235, 176–183. https://doi.org/10.1016/j.cattod.2014.02.047
[43] Muna, N.L., Mu'alimah, A.A., Pridiana, D.B., Widodo, A.K., Adiyar, S.R., Elinda, E.H., 2020. The production of biodiesel from waste cooking oil (Simultaneous esterification and transesterification using Fe/zeolite catalysts from waste geothermal). In: Materials Science Forum, Vol. 990, pp. 161–167. Trans Tech Publ. https://doi.org/10.4028/www.scientific.net/MSF.990.161
[44] Shi, Y., Xing, E., Wu, K., Wang, J., Yang, M., Wu, Y., 2017. Recent progress on upgrading of bio-oil to hydrocarbons over metal/zeolite bifunctional catalysts. Catalysis Science & Technology, 7 (12), 2385–2415. https://doi.org/10.1039/C7CY00574A
[45] Ahmedzeki, N.S., Al-Tabbakh, B.A., Antwan, M.B., Yilmaz, S., 2018. Heavy naphtha upgrading by catalytic reforming over novel bi-functional zeolite catalyst. Reaction Kinetics, Mechanisms and Catalysis, 125 (2), 1127–1138. https://doi.org/10.1007/s11144-018-1432-y
[46] Fawaz, E.G., Salam, D.A., Rigolet, S., Daou, T.J., 2021. Hierarchical zeolites as catalysts for biodiesel production from waste frying oils to overcome mass transfer limitations. Molecules, 26 (16), 4879. https://doi.org/10.3390/molecules26164879
[47] Ennaert, T., Van Aelst, J., Dijkmans, J., De Clercq, R., Schutyser, W., Dusselier, M., Verboekend, D., Sels, B.F., 2016. Potential and challenges of zeolite chemistry in the catalytic conversion of biomass. Chemical Society Reviews, 45 (3), 584–611. https://doi.org/10.1039/C5CS00859J
[48] Rahman, N.J.A., Ramli, A., Jumbri, K., Uemura, Y., 2019. Tailoring the surface area and the acid–base properties of ZrO2 for biodiesel production from Nannochloropsis sp. Scientific Reports, 9 (1), 16223. https://doi.org/10.1038/s41598-019-52771-9 | ||
|
آمار تعداد مشاهده مقاله: 362 تعداد دریافت فایل اصل مقاله: 121 |
||